Heterogeneous phthalocyanine catalyst KSM-X
Heterogeneous phthalocyanine catalyst KSM-X is produced by Akhmadullins Research and Development Center LLC according to RF patents No. 2677226 “New metal complex compounds of oligopyrocatechol and a method for obtaining catalysts for the oxidation of sulfur compounds based on them” and RF No. 2529500 “Catalyst for the oxidation of sulfur compounds” in accordance with TU 2175 -001-40655797-2014 and RPB No. 0132628813.20.62304
- The production time for a batch of catalyst is 3 months.
- The warranty period of the catalyst is 8 years.
The cost of a heterogeneous phthalocyanine catalyst KSM-X, when recalculated for a warranty period of its service of 8 years, is on average 1.5÷3 times lower than that of homogeneous analogs (a liquid catalyst is an analog of Merox).
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Heterogeneous phthalocyanine catalyst KSM-X is used in the following processes:
- gas desulfurization;
- alkaline oxidative demercaptanization of gasoline, kerosene and diesel fractions;
- demercaptanization of light oils and gas condensates;
- neutralization (purification) of sulphurous-alkaline effluents, formation waters and water process condensates.
Manufactured and supplied phthalocyanine catalyst KSM-X for:
| DIAL-Alliance LLC | 2022 |
|---|---|
| LUKOIL-Nizhegorodnefteorgsintez LLC | 2021 |
| Tomskneftekhim LLC, SIBUR | 2021 |
| LLC "FIRST PLANT" | 2020 |
| LLC "Mozyr Refinery", Republic of Belarus | 2019 |
| LUKOIL-Ukhtaneftepererabotka LLC | 2019 |
| SNPS Munaygas, Republic of Kazakhstan | 2019 |
| Kharg Petrochemical Company, Iran | 2018 |
| Syzran Oil Refinery LLC | 2018 |
| PJSC Gazpromneft-MNPZ | 2018 |
| LUKOIL-Nizhegorodnefteorgsintez LLC | 2018 |
| JSC Slavneft-Yaroslavnos | 2017 |
| PJSC Gazpromneft-Moscow Oil Refinery | 2016 |
| PJSC ANC Bashneft Ufa Refinery | 2016 |
| PJSC TAIF-NK | 2015 |
| International Station for Manufacturing of Refining, Bahrain | 2014 |
| OAO Gazpromneft-Moscow Oil Refinery | 2014 |
| LUKOIL-Nizhegorodnos LLC | 2014 |
| «ORLEN Lietuva — Мажейкский НПЗ» | 2012 |
| ORLEN Lietuva — Mazheik Oil Refinery | 2012 |
| JSC Slavneft-Yaroslavnos | 2012 |
Reference:
The KS series catalyst on a polymer carrier was developed in 1983. With its use for the oxidation of hydrogen sulfide, sulfides and mercaptides of ammonium or sodium in sulfurous-alkaline wastewater to harmless oxygen-containing compounds – thiosulfates, sulfates and alkylthiosulfonates, the LOCOS technology was developed. In 1985, the LOKOS process was first introduced at the Moscow Refinery. In 1992, using the KS catalyst, a BBF demercaptanization process was developed and implemented at the Moscow Oil Refinery – DEMERUS LPG.
In 1996, a new modification of the catalyst, KSM, was developed, and in 2012. – catalyst KSM-X, designed for the purification of liquefied hydrocarbon gases (LPG), gas condensates, gasoline, kerosene, diesel fuel and light oils from mercaptan sulfur and for the oxidative neutralization of sulfide-containing aqueous process condensates, bottom water and sulphurous-alkaline effluents in a gas, oil producing , oil refining, petrochemical, pulp and paper and other industries, also used in petrochemical synthesis for the oxidation of phenols, mercaptans and other organic and inorganic compounds.